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Hydrated metal ions in aqueous solution can act as Brønsted-Lowry acids.

A) True
B) False

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Which of the following is the strongest acid?


A) CH 3COOH
B) HF
C) H 3PO 4
D) H 2SO 3
E) H 2SO 4

F) B) and C)
G) All of the above

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If a strong acid such as HCl is diluted sufficiently with water, the pH will be higher than 7.

A) True
B) False

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All Brønsted-Lowry bases contain the hydroxide ion, OH.

A) True
B) False

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Which of the following aqueous liquids will have the highest pH?


A) 0.1 M CH 3COOH, p K a = 4.7
B) 0.1 M CuCl 2, p K a = 7.5
C) 0.1 M H 3C 6H 5O 7, p K a = 3.1
D) 0.1 M ZnCl 2, p K a = 9.0
E) Pure water

F) All of the above
G) None of the above

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Which of the following aqueous liquids is the most acidic?


A) 0.1 M Al(NO 3) 3, K a = 1 × 10 5
B) 0.1 M Be(NO 3) 2, K a = 4 × 10 6
C) 0.1 M Pb(NO 3) 2, K a = 3 × 10 8
D) 0.1 M Ni(NO 3) 2, K a = 1 × 10 10
E) Pure water

F) A) and C)
G) B) and D)

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Which of the following is the strongest acid?


A) CH 3COOH
B) HF
C) H 3PO 4
D) H 2SO 3
E) HI

F) C) and E)
G) B) and D)

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What is the value of Ka for the methylammonium ion, CH3NH3+? Kb(CH3NH2) = 4.4 × 104


A) 4.4 × 10 4
B) 4.8 × 10 6
C) 4.4 × 10 10
D) 2.3 × 10 11
E) 4.4 × 10 18

F) B) and E)
G) All of the above

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A 0.050 M solution of the weak acid HA has [H3O+] = 3.77 × 104 M. What is the Ka for the acid?


A) 7.5 × 10 3 M
B) 2.8 × 10 6 M
C) 7.0 × 10 7 M
D) 7.0 × 10 8 M
E) 2.6 × 10 11 M

F) D) and E)
G) A) and B)

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Which of the following aqueous systems has the highest pH?


A) 0.1 M HA , p K a = 11.89
B) 0.1 M HMO, p K a = 8.23
C) 0.1 M HA , p K a = 4.55
D) 0.1 M HBO, p K a = 2.43
E) Pure water

F) None of the above
G) C) and E)

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Which one of the following substances will give an aqueous solution of pH closest to 7?


A) KNO 3
B) CO 2
C) NH 4I
D) NH 3
E) CH 3NH 2

F) A) and C)
G) All of the above

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When 14.7 mL of aqueous HBr (a strong acid) was added to water, 0.482 L of a solution with a pH of 4.23 was produced. What was the molarity of the original HBr solution?


A) 1.9 × 10 3 M
B) 140 M
C) 0.288 M
D) 0.13 M
E) None of these choices are correct.

F) B) and D)
G) A) and E)

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What is the pOH of a 0.0085 M KOH solution?


A) 2.07
B) 4.77
C) 9.23
D) 11.93
E) None of these choices are correct.

F) A) and C)
G) B) and D)

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A solution is prepared by adding 0.10 mol of lithium nitrate, LiNO3, to 1.00 L of water. Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is weakly acidic.
D) The solution is strongly acidic.
E) The values for K a and K b for the species in solution must be known before a prediction can be made.

F) A) and D)
G) C) and E)

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Calcium oxide, CaO, also known as quick lime, will react with carbon dioxide to form calcium carbonate, CaCO3. Which species, if any, acts as a Lewis acid in the reaction?


A) Ca 2+
B) O 2
C) CO 2
D) CaCO 3
E) None of these choices are correct.

F) All of the above
G) A) and D)

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A solution is prepared by adding 0.10 mol of sodium fluoride, NaF, to 1.00 L of water. Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is acidic.
D) The concentrations of fluoride ions and sodium ions will be identical.
E) The concentration of fluoride ions will be greater than the concentration of sodium ions.

F) None of the above
G) B) and E)

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What is the pH of a 0.050 M LiOH solution?


A) < 1.0
B) 1.30
C) 3.00
D) 11.00
E) 12.70

F) A) and E)
G) A) and B)

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Picric acid has been used in the leather industry and in etching copper. However, its laboratory use has been restricted because it dehydrates on standing and can become shock sensitive. It has an acid dissociation constant of 0.42. What is the [H3O+] for a 0.20 M solution of picric acid?


A) 0.022 M
B) 0.052 M
C) 0.15 M
D) 0.29 M
E) None of these choices are correct.

F) B) and D)
G) A) and B)

Correct Answer

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Arsenic acid, H3AsO4, is used industrially to manufacture insecticides. Arsenic acid is a polyprotic acid with K1 = 2.5 × 104, K2 = 5.6 × 108, and K3 = 3 × 1013. What is the concentration of the HAsO42 in a solution whose initial arsenic acid concentration was 0.35 M?


A) 9.4 × 10 3 M
B) 2.5 × 10 4 M
C) 8.8 × 10 5 M
D) 5.6 × 10 8 M
E) None of these choices are correct.

F) A) and B)
G) B) and D)

Correct Answer

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Select the strongest acid from the following list.


A) HBrO 4
B) HClO
C) HBrO 2
D) HBrO
E) HIO

F) B) and E)
G) D) and E)

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